Photoelectron spectroscopy of silver and palladium cluster anions. Electron delocalization versus, localization

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Photoelectron Spectroscopy of Silver and Palladium Cluster Anions

Photoelectrons (PE) from jet-cooled mass-identified silver and palladium cluster anions (number of atoms, n < 21) were detached by UV laser light and energy-analysed in a time-of-flight (TOF) electron spectrometer of the magnetic-bottle type. For palladium PE threshold energies smoothly increase with n ; for Ag, they show clear evidence of shell effects as well as an ‘even-odd oscillation’. The...

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ژورنال

عنوان ژورنال: J. Chem. Soc., Faraday Trans.

سال: 1990

ISSN: 0956-5000,1364-5455

DOI: 10.1039/ft9908602483